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涂料工业  2018, Vol. 48 Issue (1): 75-82    https://doi.org/10.12020/j.issn.0253-4312.2018.1.75
  科学视点 |
有机硅和氟树脂在海洋防污涂料中的应用研究进展
叶章基1,2,3, 陈珊珊3, 张金伟2, 蔺存国2, 马春风1, 张广照1, 吴建华2,3
1. 华南理工大学,广州 510640;
2. 海洋腐蚀与防护国防科技重点实验室,福建厦门 361002;
3. 厦门双瑞船舶涂料有限公司,福建厦门 361101
Application of Silicone and Fluoropolymer in Marine Antifouling Coatings
Ye Zhangji1,2,3, Chen Shanshan3, Zhang Jinwei2, Lin Cunguo2,
Ma Chunfeng1, Zhang Guangzhao1, Wu Jianhua2,3
1. South China University of Technology, Guangzhou 510640, China;
2. Science and Technology on Marine Corrosionand Protection Laboratory, Xiamen, Fujian 361002, China;
3. Xiamen SunRui Ship Coating Co. Ltd, Xiamen, Fujian 361101, China
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摘要 海洋生物污损是一个世界性难题,随着人们环境保护意识的增强,发展有效的环保型海洋防污体系成为该领域最重要的研究方向。有机硅/氟基海洋防污涂料具有环保无毒的特点,是目前的研究热点之一。文章概述了有机硅和氟低表面能防污涂料的研究进展,重点介绍了基于仿生原理的有机硅/氟污损释放型防污涂料,论述了材料表面特性包括物理特性、化学特性、结构特征等对生物附着的影响,介绍了两亲性添加剂改性的有机硅防污涂料的开发,展望了污损释放型防污涂料未来的发展方向。
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叶章基
陈珊珊
张金伟
蔺存国
马春风
张广照
吴建华
关键词:  海洋防污  低表面能  污损释放  防污涂料    
Abstract: Marine biofouling is a sticky problem. As the enhancement of environmental awareness, the development of environmentally friendly marine antifouling systems has become the most important task in this field. Nowadays, non-toxic silicone/fluorine-based marine antifouling coatings have attracted considerable attention. In this paper, the recent progress in the silicon/fluorine-based low surface energy antifouling coatings have been reviewed, and particularly, the fouling release coatings based on biomimetic technology have been described. The effects of surface properties such as physical/chemical properties and structure characteristics on the settled organisms are investigated. In addition, the silicone-based antifouling coatings modified by amphiphilic additives are introduced. Finally, the future trend of the antifouling coatings is given.
Key words:  marine antifouling    low surface energy    fouling release    antifouling coatings
收稿日期:  2017-11-17                出版日期:  2018-01-01      发布日期:  2018-05-03      期的出版日期:  2018-01-01
TQ 637.3  
基金资助: “十三五”国家海洋经济创新发展示范项目(16CZB023SF12);海洋公益科研专项(201305016);福建省海洋生物资源开发利用协同创新中心产学研基金(FJMBIO1504)。
作者简介:  叶章基(1969—),男,研究员,从事舰船长效防腐防污涂料研制,检测技术及舰船材料海洋环境试验研究工作。
引用本文:    
叶章基, 陈珊珊, 张金伟, 蔺存国, 马春风, 张广照, 吴建华. 有机硅和氟树脂在海洋防污涂料中的应用研究进展[J]. 涂料工业, 2018, 48(1): 75-82.
Ye Zhangji, Chen Shanshan, Zhang Jinwei, Lin Cunguo, Ma Chunfeng, Zhang Guangzhao, Wu Jianhua. Application of Silicone and Fluoropolymer in Marine Antifouling Coatings. Paint & Coatings Industry, 2018, 48(1): 75-82.
链接本文:  
http://manu65.magtech.com.cn/Jwk3_tlgy/CN/10.12020/j.issn.0253-4312.2018.1.75  或          http://manu65.magtech.com.cn/Jwk3_tlgy/CN/Y2018/V48/I1/75
[1] SCHULTZ M P, BENDICK J A, HOLM E R, et al. Economic impact of biofouling on a naval surface ship[J]. Biofouling, 2011, 27 (1): 87-98.
[2] YEBRA D M, KILL S, JOHANSEN K D, et al. Reaction rate estimation of controlled-release antifouling paint binders: rosin-based systems[J]. Progress in Organic Coatings, 2005, 53: 256-275.
[3] DE MORA S J, STEWART C, PHILLIPS D. Sources and rate of degradation of tri(n-butyl)tin in marine sediments near Auckland, New Zealand[J]. Marine Pollution Bulletin, 1995, 30(1): 50-57.
[4] ALZIEU C L, SANJUAN J, DELTREIL J P, et al. Tin contamination in Arcachon Bay: effects on oyster shell anomalies[J]. Marine Pollution Bulletin, 1986, 17 (11): 494-498.
[5] LEJARS M, MARGAILLAN A, BRESSY C. Fouling release coatings: a nontoxic alternative to biocidal antifouling coatings[J]. Chemical Reviews, 2012, 112(8):4347-4390.
[6] 吴始栋. 船舶防污技术发展现状[J]. 船舶物资与市场, 2001(4): 46-49.
[7] MASAHITO K, AKIRA S, HIROSHI Y, et al. Antifouling painting composition: JPH10316933(A)[P]. 1998-12-02.
[8] BRADY JR R F. Formulations and field performance of fluorinated polyurethane coatings[M]. Washington D C: ACS Publication, 1998: 282-291.
[9] TRUBY K, WOOD C, STEIN J, et al. Evaluation of the performance enhancement of silicone biofouling-release coatings by oil incorporation[J]. Biofouling, 2000, 15(1-3): 141-150.
[10]STEIN J,TRUBY K, WOOD C D, et al. Silicone foul release coatings: effect of the interaction of oil and coating functionalities on the magnitude of macrofouling attachment strengths[J]. Biofouling, 2003, 19(sup1): 71-82.
[11]THOMAS J, CHOI S-B, FJELDHEIM R, et al. Silicones containing pendant biocides forantifouling coatings[J]. Biofouling, 2004, 20(4-5): 227-236.
[12]MAJUMDAR P, CROWLEY E, HTET M, et al. Combinatorial materials research applied to the development of new surface coatings XV: an investigation of polysiloxane anti-fouling/fouling-release coatings containing tethered quaternary ammonium salt groups[J]. ACS Combinatorial Science, 2011, 13(3): 298-309.
[13]MAJUMDAR P, LEE E, PATEL N, et al. Combinatorial materials research applied to the development of new surface coatings IX: an investigation of novel antifouling/fouling-release coatings containing quaternary ammonium salt groups[J]. Biofouling, 2008, 24(3): 185-200.
[14]XIE Q, MA C, LIU C, et al. Poly(dimethylsiloxane)-based polyurethane with chemically attached antifoulants for durable marine antibiofouling[J]. ACS Applied Materials & Interfaces, 2015, 7(38): 21030-21037.
[15]CARLOS A B. Incor poration of zosteric acid into silicone coatings to deter fresh water bacteria attachment[D]. Ohio:University of Akron.2004.
[16]LEJARS M, MARGAILLAN A, BRESSY C. Well-defined graft copolymers of tert-butyldimethylsilyl methacrylate and poly(dimethylsiloxane) macromonomers synthesized by RAFT polymerization[J]. Polymer Chemistry, 2013, 4(11):3282-3292.
[17]AMIROJI K, HIROTA N, MORIMOTO K, et al. Non-toxic anti-foul coating composition: JPH01306479(A)[P]. 1989-12-11.
[18]LIU C, XIE Q, MA C,et al. Fouling release property of polydimethylsiloxane-based polyurea with improved adhesion to substrate[J]. Industrial & Engineering Chemistry Research, 2016, 55: 6671-6676.
[19]FANG J, KELARAKIS A, WANG D, et al. Fouling release nanostructured coatings based on PDMS-polyurea segmented copolymers[J]. Polymer, 2010, 51(12): 2636-2642.
[20]MAJUMDAR P, WEBSTER D C. Preparation of siloxane-urethane coatings having spontaneously formed stable biphasic microtopograpical surfaces[J]. Macromolecules, 2005, 38(14): 5857-5879.
[21]RATH S K, CHAVAN J G, SASANE S, et al. Two component silicone modified epoxy foul release coatings: effect of modulus, surface energy and surface restructuring on pseudobarnacle and macrofouling behavior[J]. Applied Surface Science, 2010, 256(8): 2440-2406.
[22]STEIN J, TRUBY K, WOOD C D, et al. Structure-property relationships of silicone biofouling-release coatings: effect of silicone network architecture on pseudobarnacle attachment strengths[J]. Biofouling, 2003, 19(2): 87-94.
[23]BEIGBEDER A, DEGEE P, CONLAN S L, et al. Preparation and characterisation of silicone-based coatings filled with carbon nanotubes and natural sepiolite and their application as marine fouling-release coatings[J]. Biofouling, 2008, 24(4): 291-302.
[24]RAFIEE J, RAFIEE M A, YU Z Z, et al. Superhydrophobic to superhydrophilic wetting control in graphene films[J]. Advanced Materials, 2010, 22(19): 2151-2154.
[25]LIU C, XIE Q, MA C,et al. Self-repairing silicone coatings for marine anti-biofouling[J]. Journal of Materials Chemistry A, 2017, 5: 15855-15861.
[26]BRADY JR R F, BONAFEDE S J, SCHMIDT D L. Self-assembled water-borne fluoropolymer coatings for marine fouling resistance[J]. Surface Coatings International Part B: Coatings Transactions, 1999, 82(12): 582-585.
[27]田军, 辜志俊, 李克恭, 等. 低表面能材料上海生物附着的研究[J]. 涂料工业, 1998,28(1): 11-14.
[28]田军, 薛群基. 无毒防污涂层表面的化学结构研究[J]. 环境科学, 1998 (1): 46-49.
[29]张人韬. 水性氟硅涂料及其自分层效果研究[J]. 新型建筑材料, 2002 (6): 19-21.
[30]BRADY R F, Robust nontoxic antifouling elastomers: US20030190482[P]. 2003-06-19.
[31]BONAFEDE S J, BRADY JR R F. Compositional effects on the fouling resistance of fluorourethane coatings[J]. Surface Coatings International Part B: Coatings Transactions, 1998, 81(4): 181-185.
[32]王华进, 王贤明, 管朝祥, 等. 海洋防污涂料的发展[J]. 涂料工业, 2003,33(3): 35-38.
[33]YARBROUGH J C, ROLLAND J P, DESIMONE J M, et al. Contact angle analysis, surface dynamics, and biofouling characteristics of cross-linkable, random perfluoropolyether-based graft terpolymers[J]. Macromolecules, 2006, 39(7): 2521-2528.
[34]JEON J H, PARK Y G, LEE Y H, et al. Preparation and properties of UV-curable fluorinated polyurethane acrylates containing crosslinkable vinyl methacrylate for antifouling coatings[J]. Journal of Applied Polymer Science, 2015, 132(26):1-10.
[35]MERA ANNE, WYNNE KENNETH J. Fluorinated silicone resin fouling release composition: US6265515(B1)[P]. 2001-07-24.
[36]MIELCZARSKI J A, MIELCZARSKI E, GALLI G, et al. The surface-segregated nanostructure of fluorinated copolymer-poly(dimethylsiloxane) blend films[J]. Langmuir, 2010, 26(4): 2871-2876.
[37]MARABOTTI I, MORELLI A, ORSINI L M, et al. Fluorinated/siloxane copolymer blends for fouling release: chemical characterisation and biological evaluation with algae and barnacles[J]. Biofouling, 2009, 25(6): 481-493.
[38]BERGLIN M, WYNNE K J, GATENHOLM P. Fouling-release coatings prepared from α, ω-dihydroxypoly(dimethylsiloxane) cross-linked with (heptadecafluoro-1,1,2,2-tetrahydrodecyl)triethoxysilane[J]. Journal of colloid and interface science, 2003, 257(2): 383-391.
[39]POLLACK K A, IMBESI P M, RAYMOND J E, et al. Hyperbranched fluoropolymer-polydimethylsiloxane-poly(ethylene glycol) cross-linked terpolymer networks designed for marine and biomedical applications: heterogeneous nontoxic antibiofouling surfaces[J]. Acs Applied Materials & Interfaces, 2014, 6(21):19265-19274.
[40]BIXLER G D, BHUSHAN B. Biofouling: lessons from nature[J]. Philosophical Transactions of the Royal Society of London A: Mathematical, Physical and Engineering Sciences, 2012, 370(1967): 2381-2417.
[41]叶章基, 王晶晶, 蔺存国, 等. 舰船高性能防腐蚀防污涂料研究进展[J]. 中国材料进展, 2014, 3(7): 418-425.
[42]张金伟, 郑纪勇, 王利, 等. 仿生防污材料的研究进展[J]. 中国材料进展, 2014, 33(2): 86-92.
[43]AYDA G, NURIOGLU A, CATARINA C, et al. Non-toxic, non-biocide-release antifouling coatings based on molecular structure design for marine applications.[J]. Journal of Materials Chemistry B, 2015, 3, 6547-6570.
[44]SCHULTZ M P. Effects of coating roughness and biofouling on ship resistance and powering[J]. Biofouling, 2007, 23(5-6): 331-341.
[45]JIANG S, CAO Z. Ultralow-fouling, functionalizable, and hydrolyzable zwitterionic materials and their derivatives for biological applications[J]. Advanced Materials, 2010, 22(9): 920-932.
[46]FERRARI M, BENEDETTI A. Superhydrophobic surfaces for applications in seawater[J]. Advances in Colloid and Interface Science, 2015, 222: 291-304.
[47]GUDIPATI C S, GREENLIEF C M, JOHNSON J A, et al. Hyperbranched fluoropolymer and linear poly(ethylene glycol) based amphiphilic crosslinked networks as efficient antifouling coatings: an insight into the surface compositions, topographies, and morphologies[J]. Journal of Polymer Science Part A: Polymer Chemistry, 2004, 42 (24): 6193-6208.
[48]YANG W J, NEOH K G, KANG E T, et al. Polymer brush coatings for combating marine biofouling[J]. Progress in Polymer Science, 2014, 39(5): 1017-1042.
[49]BODKHE R B, STAFSLIEN S J, DANIELS J, et al. Zwitterionic siloxane-polyurethane fouling release coatings[J]. Progress in Organic Coatings, 2015, 78: 369-380.
[50]XIE L, HONG F, HE C, et al. Coatings with a self-generating hydrogel surface for antifouling[J]. Polymer, 2011, 52(17): 3738-3744.
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